temephos removal from water samples by silver modified zero-valent iron nanoparticles

Authors

roohollah shiralipour chemistry department, college of science, shahid chamran university, ahvaz, ir iran; chemistry department, college of science, shahid chamran university, ahvaz, ir iran. tel: +98-6133360018, fax: +98-6133337009

behrooz zargar chemistry department, college of science, shahid chamran university, ahvaz, ir iran

hooshang parham chemistry department, college of science, shahid chamran university, ahvaz, ir iran

abstract

conclusions briefly, the current study represents a novel method to eliminate temephos as an organophosphate compound from water samples with modified zero-valent iron nanoparticles. background temephos is an organophosphate pesticide used as larvicide in the environment. although not extremely hazardous, it can be risky for human health in the moderate concentrations. objectives this study investigated the quantitative removal efficiency of temephos, an organophosphate pesticide, from contaminated water by silver-modified zvinps. in addition, the operational parameters affected on removal process were optimized. materials and methods in the current study, three water samples from different parts of iran such as ahvaz tap water, the karoon river passing through khoramshahr city, and the caspian sea were collected. a new method for effective removal of temephos from the sample solutions by silver modified zero-valent iron nanoparticles as an efficient adsorbent was introduced. results for a typical solution in which temephos was removed about 21% by iron zero-valent nanoparticles, modification by silver improved removal method was up to about 99%. the required time for the complete removal of temephos was about eight minutes. variation of ph and concentration of kno3 as an electrolyte was considerably ineffective on the efficient temephos removal. adsorption studies of the method were followed by langmuir isotherm. maximum temephos adsorption amount was 12.65 mg/g under optimal conditions. the proposed method was simple, fast and safe to treat temephos polluted waters. preparation of the adsorbent was easy and removal time was short.

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Journal title:
jundishapur journal of health sciences

جلد ۷، شماره ۱، صفحات ۰-۰

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